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微软官方从.NET Framework 4之后不再支持System.Web.Security.FormsAuthentication.HashPasswordForStoringInConfigFile(string password, string passwordFormat)方法。MD5加密需要自行实现。需要注意的是该方法加密结果是小写，而
HashPasswordForStoringInConfigFile加密结果是大写

public static string MD5Encrypt(string input)
{
	StringBuilder builder = new StringBuilder();
        using (MD5CryptoServiceProvider md5Crypto = new MD5CryptoServiceProvider())
        {
            byte[] data = md5Crypto.ComputeHash(Encoding.UTF8.GetBytes(input));
            for (int i = 0; i < data.Length; i++)
            {
                builder.Append(data[i].ToString("x2"));
            }
        }
        return builder.ToString();
}

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using System;
using System.Text;
using System.Security.Cryptography;

namespace Utility.Security
{
    /// <summary>
    /// DES加密/解密类。
    /// </summary>
    public class DESEncrypt
    {
        /// <summary> 
        /// 加密数据 
        /// </summary> 
        public static string Encrypt(string Text, string sKey)
        {
            DESCryptoServiceProvider des = new DESCryptoServiceProvider();
            byte[] inputByteArray;
            inputByteArray = Encoding.Default.GetBytes(Text);
            des.Key = ASCIIEncoding.ASCII.GetBytes(System.Web.Security.FormsAuthentication.HashPasswordForStoringInConfigFile(sKey, "md5").Substring(0, 8));
            des.IV = ASCIIEncoding.ASCII.GetBytes(System.Web.Security.FormsAuthentication.HashPasswordForStoringInConfigFile(sKey, "md5").Substring(0, 8));
            System.IO.MemoryStream ms = new System.IO.MemoryStream();
            CryptoStream cs = new CryptoStream(ms, des.CreateEncryptor(), CryptoStreamMode.Write);
            cs.Write(inputByteArray, 0, inputByteArray.Length);
            cs.FlushFinalBlock();
            StringBuilder ret = new StringBuilder();
            foreach (byte b in ms.ToArray())
            {
                ret.AppendFormat("{0:X2}", b);
            }
            return ret.ToString();
        }

        /// <summary> 
        /// 解密数据 
        /// </summary> 
        public static string Decrypt(string Text, string sKey)
        {
            DESCryptoServiceProvider des = new DESCryptoServiceProvider();
            int len;
            len = Text.Length / 2;
            byte[] inputByteArray = new byte[len];
            int x, i;
            for (x = 0; x < len; x++)
            {
                i = Convert.ToInt32(Text.Substring(x * 2, 2), 16);
                inputByteArray[x] = (byte)i;
            }
            des.Key = ASCIIEncoding.ASCII.GetBytes(System.Web.Security.FormsAuthentication.HashPasswordForStoringInConfigFile(sKey, "md5").Substring(0, 8));
            des.IV = ASCIIEncoding.ASCII.GetBytes(System.Web.Security.FormsAuthentication.HashPasswordForStoringInConfigFile(sKey, "md5").Substring(0, 8));
            System.IO.MemoryStream ms = new System.IO.MemoryStream();
            CryptoStream cs = new CryptoStream(ms, des.CreateDecryptor(), CryptoStreamMode.Write);
            cs.Write(inputByteArray, 0, inputByteArray.Length);
            cs.FlushFinalBlock();
            return Encoding.Default.GetString(ms.ToArray());
        }
    }
}